Insertion of SO2 into a Sulfide-Bridged M-Ge Bond: Synthesis, Characterization, and Reactivity of the O-Germyl-S-sulfoxylate

Academic Article

Abstract

  • Addition of SO2to (Et3P)2Pd(μ -S)Ge[N(SiMe3)2]2 (1) results in the insertion of SO2 into the Pd-Ge bond to give the O-germyl-S-sulfoxylate insertion isomer (Et3P)2Pd(μ-S)S(O)OGe[N(SiMe 3)2]2 (2). Heating solutions of 2 results in the formation of (Et3P)Pd(SGe[N(SiMe3)2] 2OSOGe[N(SiMe3)2]2S) (3) and a LnPd(0) fragment. X-ray crystal structures of 2 and 3 are reported.
  • Digital Object Identifier (doi)

    Author List

  • Cygan ZT; Kampf JW; Holl MMB
  • Start Page

  • 2057
  • End Page

  • 2063
  • Volume

  • 43
  • Issue

  • 6