Synthesis and molecular structural studies of a series of orthometalated dimers [RAIN(t-Bu)-μ-(CH2C6H4)]2, where R = Me, Et, n-Pr, n-Bu, i-Bu

Academic Article

Abstract

  • The orthometalated aluminum-nitrogen dimer series [RAIN(t-Bu)-μ-(CH C H )] (R = Me, 1; Et, 2; n-Pr, 3; n-Bu, 4; i-Bu, 5) was synthesized by thermolysis of 1:1 mixtures of R Al with HN(t-Bu)CH Ph. The reaction times and temperatures required for orthometalation, the molecular structural data, and the H and C NMR spectral parameters of the dimers are compared with the reported data for the series [RAIN-(CH Ph)-μ-(CH C H )] . 2 6 4 2 3 2 2 2 6 4 2 1 13
  • Published In

  • Organometallics  Journal
  • Digital Object Identifier (doi)

    Author List

  • Kekia OM; Watkins CL; Krannich LK; Rheingold AL; Liable-Sands LM
  • Start Page

  • 582
  • End Page

  • 585
  • Volume

  • 20
  • Issue

  • 3