Gas-phase thermodynamic models of nitrogen-induced nanocrystallinity in chemical vapor-deposited diamond

Academic Article

Abstract

  • Gas-phase thermodynamic equilibrium calculations involving H 2/CH4/N2 mixtures were performed to investigate the chemical interactions leading to nitrogen-induced nanocrystallinity in microwave plasma chemical vapor deposition of diamond films. The strong influence of the CN radical in causing nanocrystallinity is confirmed by the correlation of its modeled composition in the gas phase with the degree of nanocrystallinity as determined experimentally for diamond films grown with different N2 additions. For a given CH4 feedgas concentration, there exists a critical N2 feedgas concentration, above which the change in the CH3/CN ratio is minimal and further induced nanocrystallinity is diminished. This is verified experimentally where it is observed that the same critical N2 feedgas concentration exists, above which a further decrease in diamond crystallinity and surface roughness of the grown diamond films is minimal. © 2002 American Institute of Physics.
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    Digital Object Identifier (doi)

    Author List

  • Corvin RB; Harrison JG; Catledge SA; Vohra YK
  • Start Page

  • 2550
  • End Page

  • 2552
  • Volume

  • 80
  • Issue

  • 14