X-ray crystal structure of trans-PdCl2(PPh2C 12H7S3)2, a new morphology

Academic Article

Abstract

  • Herein we report the crystal structure of trans-PdCl2(PPh 2C12H7S3)2, 1, in a different morphology than has previously been reported [Stott et al. (Dalton Trans (4):652-653, 2005]. This structure crystallizes in a P-1 space group with a = 9.4249(19) Å, b = 11.540(2) Å, c = 12.559(3) Å, α = 79.07(3)°, β = 78.04(3)°, γ = 69.44(3)°, Z = 1. The earlier structure possessed a P21/n space group. Additionally the terthienyl moieties of 1 demonstrate the anti orientation exclusively while the P21/n space group structure has some syn and even syn/anti mixed geometries included. © 2007 Springer Science+Business Media, LLC.
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    Digital Object Identifier (doi)

    Author List

  • Myrex RD; Owens SB; Gray GM
  • Start Page

  • 549
  • End Page

  • 553
  • Volume

  • 37
  • Issue

  • 8