Palmadorins A-C, diterpene glycerides from the antarctic nudibranch austrodoris kerguelenensis

Academic Article

Abstract

  • The nudibranch Austrodoris kerguelenensis is distributed widely around the Antarctic coast and continental shelves. Earlier collections from. McMurdo Sound and the Weddell Sea shelf have afforded a suite of diterpene glyceride esters, a compound class implicated as a chemical defense in nudibranchs. The present chemical investigation of A. kerguelenensis collected near Palmer Station on the Western Antarctic Peninsula has revealed additional examples, palmadorins A-C (1-3), as the first three members of a new series of clerodane diterpenes. In this paper we describe their isolation, structure elucidation, and stereochemical analysis using a combination of one- and two-dimensional NMR spectroscopy and wet chemical methods. © 2010 American Chemical Society and American Society of Pharmacognosy.
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    Digital Object Identifier (doi)

    Author List

  • Diyabalanage T; Iken KB; McClintock JB; Amsler CD; Baker BJ
  • Start Page

  • 416
  • End Page

  • 421
  • Volume

  • 73
  • Issue

  • 3