Asymmetric copper-catalysed alkene cyclopropanation and aziridination using tartrate-derived bis-oxazoline ligands

Academic Article

Abstract

  • The enantioselective cyclopropanation and aziridination of styrene using chiral tartrate-derived bis-oxazoline ligands 1, 6, and 7 is reported. The effects of variation of the size of the oxazoline substituent (R 1 ) and the size of the diazoacetate ester substituent (R 2 ) on the level and sense of enantioselection is described.
  • Authors

    Published In

    Digital Object Identifier (doi)

    Author List

  • Harm AM; Knight JG; Stemp G
  • Start Page

  • 6189
  • End Page

  • 6192
  • Volume

  • 37
  • Issue

  • 34