New high-pressure phase transition in zirconium metal

Academic Article

Abstract

  • Phase transitions in the group-IV transition-metal zirconium were studied by the energy-dispersive x-ray-diffraction technique with a synchrotron source to a pressure of 32 GPa. A first-order phase transition between an phase and a bcc phase (isostructural with group-V transition elements) was observed during compression and decompression in a pressure range of 30+2 GPa, which is in qualitative agreement with the recent first principles theoretical predictions. The observation of the bcc phase in Zr (a group-IV element) under pressure at room temperature signifies a pressure-induced electronic configuration similar to that of a group-V element. © 1990 The American Physical Society.
  • Authors

    Published In

    Digital Object Identifier (doi)

    Author List

  • Xia H; Duclos SJ; Ruoff AL; Vohra YK
  • Start Page

  • 204
  • End Page

  • 207
  • Volume

  • 64
  • Issue

  • 2