Synthesis and structural studies of hydrophilic mesocyclic trithioethers

Academic Article

Abstract

  • The functionalized mesocyclic trithioethers, 1,4,7-trithiacyclodecane-9,9-dimethanol (10S3-diMeOH), 9-methyl-1,4,7-trithiacyclodecane-9-carboxylic acid (Me-10S3-acid), 1,4,7-trithiacycloundecane-9,10-diol (dihydroxy-11S3), 1,5,9-trithiacyclododecane-3,3-dimethanol (12S3-diMeOH), 3-methyl-1,5,9-trithiacyclododecane-3-carboxylic acid (Me-12S3-acid), and 1,5,9-trithiacyclotridecane-11, 12-diol(dihydroxy-13S3), have been synthesized using the cesium dithiolate technique. The single-crystal X-ray structure has been determined for 3-methyl-1,5,9-trithiacyclododecane-3-carboxylic acid. The compound crystallizes in the monoclinic space group P2 /n, with a = 9.513(2) Å, b = 5.706(1) Å, c = 25.70(1) Å, β = 96.50(1)°, Z = 4, and R = 0.075. © 1998 John Wiley & Sons, Inc. 1
  • Authors

    Published In

    Author List

  • Setzer WN; Liou SY; Easterling GE; Simmons RC; Gullion LM; Meehan EJ; Grant GJ; Gray GM
  • Start Page

  • 123
  • End Page

  • 128
  • Volume

  • 9
  • Issue

  • 2