Organometallics

Journal

Publication Venue For

  • Correlating the Activity of Rhodium(I)-Phosphite-Lariat Ether Styrene Hydroformylation Catalysts with Alkali Metal Cation Binding through NMR Spectroscopic Titration Methods.  35:2609-2620. 2016
  • Triaryl-Like MONO-, BIS-, and TRISKITPHOS Phosphines: Synthesis, Solution NMR Studies, and a Comparison in Gold-Catalyzed Carbon-Heteroatom Bond Forming 5-exo-dig and 6-endo-dig Cyclizations.  35:1265-1278. 2016
  • Metallathiacrown Ethers: Synthesis and Characterization of Transition-Metal Complexes Containing α,ω-Bis(phosphite)-Polythioether Ligands and an Evaluation of Their Soft Metal Binding Capabilities.  34:4605-4617. 2015
  • Palladium-catalyzed suzuki-miyaura cross-couplings with 2-diethylphosphonato-substituted aryl-and naphthylboronate esters as the nucleophilic partner: A complementary approach to the synthesis of biaryl monophosphonates.  33:5209-5219. 2014
  • Erratum: Addition to vanadocene de novo: Spectroscopic and computational analysis of bis(η5-cyclopentadienyl)vanadium(II) (Organometallics (2012) 31 (23) (8265-8274) DOI: 10.1021/om300892y).  33:1325. 2014
  • Electron-rich trialkyl-type dihydro-KITPHOS monophosphines: Efficient ligands for palladium-catalyzed suzuki-miyaura cross-coupling. Comparison with their biaryl-like KITPHOS monophosphine counterparts.  32:1773-1788. 2013
  • Vanadocene de novo: Spectroscopic and computational analysis of bis(η5-cyclopentadienyl)vanadium(II).  31:8265-8274. 2012
  • Generally applicable NMR titration methods for the determination of equilibrium constants for coordination complexes: Syntheses and characterizations of metallacrown ethers with α,ω-bis(phosphite)- Polyether ligands and determination of equilibrium binding constants to li+.  30:5695-5709. 2011
  • Ruthenium complexes of κ(P)-and κ(P)-η6- coordinated KITPHOS monophosphines: Efficient catalysts for the direct ortho arylation of 2-phenylpyridine and N-phenylpyrazole with aryl chlorides.  30:6010-6016. 2011
  • Efficient cycloisomerization of propargyl amides by electrophilic gold(I) complexes of KITPHOS monophosphines: A comparative study.  29:4139-4147. 2010
  • Study of the effects of alkali metal salts on styrene hydroformylation reactions catalyzed by rhodium(I) complexes of bis(phosphite) ligands.  27:4282-4287. 2008
  • Biaryl-like CATPHOS diphosphines via double diels-alder cycloaddition between 1,4-bis(diphenylphosphinoyl)buta-1,3-diyne and anthracenes: Efficient ligands for the palladium-catalyzed amination of aromatic bromides and α-arylation of ketones.  27:1679-1682. 2008
  • Efficient asymmetric carbonyl-ene reactions catalyzed by platinum metal lewis acid complexes of conformationally flexible NUPHOS diphosphines: A comparison with BINAP.  26:6453-6461. 2007
  • Metal-dependent reactivity of electrophilic platinum group metal lewis acid catalysts: Competitive alkene dimerization, intramolecular friedel-crafts alkylation, and carbonyl-ene reactivity.  26:5961-5966. 2007
  • Asymmetric hydrogenation of ketones with ruthenium complexes of rac- and enantiopure (S,S)-1,2-bis((diphenylphosphino)methyl)cyclohexane: A comparative study with rac- and (R)-BINAP.  26:2465-2468. 2007
  • Synthesis and characterization of transition metal systems containing phosphino-oligothiophene ligands for nonlinear optical materials.  25:5045-5050. 2006
  • Modular synthesis of a new class of bis(amino-oxazoline) using palladium-catalyzed Buchwald-Hartwig amination methodology.  25:4341-4350. 2006
  • Ruthenium complexes of six-electron-donor NUPHOS-Type diphosphines: Highly selective catalysts for the hydrocarboxylation of terminal alkynes.  24:2633-2644. 2005
  • Highly efficient asymmetric hetero-diels-alder reactions of carbonyl compounds catalyzed by Lewis acid platinum complexes of conformationally flexible NUPHOS-type diphosphines.  23:6127-6133. 2004
  • Unusual hydrolysis reactions of cis-Bis((2,2′-biphenylylene) phosphochloridite ester)tetracarbonylmolybdenum(O).  23:3239-3245. 2004
  • Comparative study of diastereoisomer interconversion in chiral BINOL-ate and diamine platinum complexes of conformationally flexible NUPHOS diphosphines.  23:1055-1064. 2004
  • Synthesis and characterization of cyclic oligomeric [cis-Mo(CO)4(Ph2P(C4H2S)2 PPh2)]n and model complexes for the edge and corners in the cyclic oligomer.  23:409-415. 2004
  • Nucleophilic displacement reactions of cis-bis((2,2′-biphenylylene)phosphochloridite ester)tetracarbonylmolybdenum(0). The first example of an unusual hydrolysis reaction yielding unsymmetrically substituted products.  22:4198-4205. 2003
  • Ruthenium complexes of the 1,4-bis(diphenylphosphino)-1,3-butadiene-bridged diphosphine 1,2,3,4-Me4-NUPHOS: Solvent-dependent interconversion of four- and six-electron donor coordination and transfer hydrogenation activity.  22:1452-1462. 2003
  • Synthesis, NMR characterization, and cation binding of metallacrown ethers with asymmetric Bis(phosphinite) and bis(phosphite) ligands derived from 2-hy droxy-2′-(1,4,7-trisoxo-9-nonanol)-1,1′-biphenyl.  22:1081-1088. 2003
  • Synthesis and molecular structure studies of [Me2AlN(i-Pr)CH2PH]2 and the related orthometalated dimers [RAlN(i-Pr)-μ-(CH2C6H4)]2, where R = Me, n-Pr, n-Bu, i-Bu.  21:5987-5990. 2002
  • Synthesis of a new class of 1,4-bis(diphenylphosphino)-1,3-butadiene bridged diphosphine, NUPHOS, via zirconium-mediated reductive coupling of alkynes and diynes: Applications in palladium-catalyzed cross-coupling reactions.  21:1383-1399. 2002
  • Synthesis and molecular structural studies of a series of orthometalated dimers [RAIN(t-Bu)-μ-(CH2C6H4)]2, where R = Me, Et, n-Pr, n-Bu, i-Bu.  20:582-585. 2001
  • Remarkable differences in catalyst activity and selectivity for the production of methyl propanoate versus CO-ethylene copolymer by a series of palladium complexes of related C4-bridged diphosphines.  19:4957-4967. 2000
  • Synthesis, NMR characterization, and molecular structural studies of a series of ortho-metalated aluminum-nitrogen dimers.  19:3253-3256. 2000
  • Solution Conformational Features of the Unsymmetrical Metalla Crown Ether cis-Mo(CO)4{2-(2,2′-O2C12H 8)PO(CH2CH2O)2-2-C 20H12-2′-OP(2,2′-O2C 12H8)} from 2D NMR Spectroscopy and Molecular Modeling.  19:1232-1238. 2000
  • 31P NMR and X-ray crystallographic study of atropisomerism in cis-tetracarbonylmolybdenum(0) and cis-dichloroplatinum(II) complexes of (±)-6,6′-[[1,1′-Biphenyl]-2,2′-diylbis(oxy)] bis(dibenzo[d,f]-[1,3,2]dioxaphosphepin) and (±)-6,6′-[[1,1′-Binaphthyl]-2,2′-diylbis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) ligands.  18:2593-2600. 1999
  • 31 P NMR and X-ray Crystallographic Study of Atropisomerism in cis -Tetracarbonylmolybdenum(0) and cis -Dichloroplatinum(II) Complexes of (±)-6,6‘-[[1,1‘-Biphenyl]-2,2‘-diylbis(oxy)]bis(dibenzo[ d , f ]- [1,3,2]dioxaphosphepin) and (±)-6,6‘-[[1,1‘-Binaphthyl]- 2,2‘-diylbis(oxy)]bis(dibenzo[ d , f ][1,3,2]dioxaphosphepin) Ligands.  18:2593-2600. 1999
  • Addition of a phenyl phosphinidene complex to conjugated diynes.  18:796-799. 1999
  • Synthesis and characterization of an orthometalated aminoalane, [MeAlN(CH2Ph)-μ-(CH2C6H4)] 2: Molecular structures of [MeAlN(CH2Ph)-μ-(CH2C6H4)] 2 and [Me2AlN(CH2Ph)2]2.  17:4319-4321. 1998
  • Conformationally restrained octahedral metallacrown ethers with 1,2-(Ph2P(CH2CH2O)2) 2C6H4 ligands. X-ray crystal structure of cis-Mo(CO)4{1,2-(Ph2P(CH2CH2O) 2)2C6H4-P,P′}.  17:3550-3556. 1998
  • Synthesis and molecular structure of an orthometalated aminogallane, [MeGaN(CH2C6H4)(CH2Ph)]2.  15:5641-5644. 1996
  • Reactivity of R2AlH (R = Me, Bui) and Me3M (M = Al, Ga, In) toward the silylphosphines P(SiMe3)3 and HP(SiMe3)2.  15:3980-3984. 1996
  • Reactivity of R2AlH (R = Me, Bui) with selected aminoarsines and secondary amines.  15:2458-2464. 1996
  • H2- versus HSiMe3-Elimination in the Reactivity of HP(SiMe3)2 with Me2AlH To Yield a Mixed Organoaluminum Phosphide Trimer.  14:3094-3097. 1995
  • Size-Selective Reactions of cis-Mo(CO)4{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'} (n = 4, 5) Metallacrown Ethers with Mercury(II) Salts. Crystal Structure of cis-Mo(CO)4{.mu.-Ph2P(CH2CH2O)5CH2CH2PPh2-P,P',O,O',O'',O''',O''''}.cntdot.HgCl2, an Unusual Bimetallic Complex Containing a Molecular Cleft.  14:245-250. 1995
  • Size-Selective Reactions of cis-Mo(CO)4{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'} (n = 4, 5) Metallacrown Ethers with Mercury(II) Salts. Crystal Structure of cis-Mo(CO)4{μ-Ph2P(CH2CH2O)5CH2CH2PPh2-P,P',O,O',O″,O‴,O‴}•HgCl2, an Unusual Bimetallic Complex Containing a Molecular Cleft.  14:245-250. 1995
  • [cie,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'}]m(n = 4, 5; m = 1, 2,…) Metallacrown Ethers. X-ray Crystal Structures of cie,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}, a Complex Which Exhibits Rotational Isomers in the Solid State, and [cis,cis,trans-RuCl2(CO)2-{μ-Ph2P(CH2CH2O)4(CH2CH2PPh2-P,P'}]2, an Unusual Dimetallacrown Ether.  14:238-244. 1995
  • [cis,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)nCH2CH2PPh2-P,P'}]m (n = 4, 5; m = 1, 2, ...) Metallacrown Ethers. X-ray Crystal Structures of cis,cis,trans-RuCl2(CO)2{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}, a Complex Which Exhibits Rotational Isomers in the Solid State, and [cis,cis,trans-RuCl2(CO)2{.mu.-Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}]2, an Unusual Dimetallacrown Ether.  14:238-244. 1995
  • Synthesis and X-ray Crystal Structure of trans-Mo(CO)4{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P′}, a Molecular Gyroscope Formed by Trans Coordination of a Bis(phosphine) Ligand in an Octahedral Metal Complex.  13:1542-1544. 1994
  • Synthesis and a Multinuclear NMR Spectroscopic Study of Some Mo(CO)5(PPh2XR) (X = O, NH; R = 1-4 Carbon Alkyls) Complexes. Steric Effects on 31P and 95Mo Chemical Shifts.  2:1026-1031. 1983
  • International Standard Serial Number (issn)

  • 0276-7333
  • Electronic International Standard Serial Number (eissn)

  • 1520-6041